The Single Event Probability Calculator uses the following formula (among others):
P(E) = n(E) / n(T) = (number of outcomes in the event) / (total number of possible outcomes)
The answer will be a number between 0 (not probable - The train did not arrive at the desired or acceptable time) and 1 (the train arrived each time it was scheduled within your specified time).
Reliability (statistically speaking) is another term for consistency. If the train arrives several times within your specified time period, the train arrival is consistent. Again, Reliability will be a percentage between 0 (unreliable) and 100 (reliable).
You should specify a tolerance - the amount you will accept for being early as opposed to late or absent. Then, work backwards to give you the amount of acceptable time to wait for your appointment by being early. What is the range of arrival times (variability) of the transportation method you've chosen? Incorporate that into your calculation since you cannot affect this but must tolerate this as part of the system. If the train has no record of being more than X minutes late, use that or a multiple of that into your tolerance.
If the train arrives once a day, you might want to arrive a day early to ensure you have ample time to arrive at your appointment.
If all this is relevant (It is), you might want to check on the validity of your assumptions and intentions.
Such calculations are relatively easy to compute. The difficult part is the interpretation of the results and adopting a course of action based on the calculations.
For example: What if the probability is 0.66 and is 99.9% reliable?
Good luck.